Name: 
 

2nd Semester Test Review



Multiple Choice
Identify the choice that best completes the statement or answers the question.
 

 1. 

In the reaction SO2Cl2 mc001-1.jpg SO2+Cl2 heat is evolved. What happens when chlorine (Cl2) is added to the equilibrium mixture at constant volume?
a.
The temperature of the system increases.
b.
The temperature of the system decreases.
c.
More chlorine is produced.
d.
The temperature remains unaffected.
 

 2. 

A(n)  _____ solution contains the maximum amount of dissolved solute for a given amount of solvent.
a.
saturated
c.
suspended
b.
supersaturated
d.
unsaturated
 

 3. 

Unlike in an ideal gas, in a real gas
a.
all particles move in the same direction.
b.
all particles have the same kinetic energy.
c.
the particles cannot diffuse.
d.
the particles can exert attractive forces on each other.
 

 4. 

The equilibrium constant for this reaction at 700.0 K is 0.44.  mc004-1.jpg <->  mc004-2.jpg
What is the concentration of carbon dioxide gas, if [H2O] = 0.16 mol/L, [CO2] = 0.15 mol/L and [H2] = 0.14 mol/L?
a.
0.0014 mol/L
c.
0.16 mol/L
b.
0.075
d.
0.75 mol/L
 

 5. 

Water running over soil will cause:
a.
chemical weather
c.
Global warming
b.
Erosion
d.
Adhesion
 

 6. 

A(n) _____ solution contains more dissolved solute than a saturated solution at the same temperature.
a.
saturated
c.
suspended
b.
supersaturated
d.
unsaturated
 

 7. 

Which of the following statements about a catalyst is true?
a.
A catalyst can initiate a reaction.
b.
A catalyst can accelerate a reaction.
c.
A catalyst can be consumed during a reaction.
d.
A catalyst can be changed during a reaction.
 

 8. 

What volume of oxygen is needed to react with solid sulfur to form 6.20 L of sulfur dioxide?
a.
6.20 L
c.
12.4 L
b.
7.20 L
d.
99.2 L
 

 9. 

According to Le Chatelier’s principle, when the volume is increased, the equilibrium shifts to the right for only one of the following. For which of the following reversible reactions is this true?
a.
mc009-1.jpg
b.
mc009-2.jpg
c.
mc009-3.jpg
d.
mc009-4.jpg
 

 10. 

Which substance has the most space between its particles?
a.
H2O(g)
c.
H2O(s)
b.
H2O(l)
d.
all have the same space
 

 11. 

The __________ law of thermodynamics states that spontaneous processes always proceed in such a way that the entropy of the universe increases.
a.
first
c.
third
b.
second
d.
fourth
 

 12. 

If a collision between molecules is very gentle, the molecules are
a.
more likely to be oriented favorably.
b.
less likely to be oriented favorably.
c.
likely to react.
d.
likely to rebound without reacting.
 

 13. 

A solution that contains equal concentrations of hydrogen and hydroxide ions is _____.
a.
an acid
c.
neutral
b.
a base
d.
ionized
 

 14. 

A substance that does not dissolve in a solvent is said to be:
a.
insoluble
c.
miscible
b.
immiscible
d.
soluble
 

 15. 

More solute can be dissolved in a _____ solution:
a.
saturated
c.
suspended
b.
supersaturated
d.
unsaturated
 

 16. 

Which system has the lowest entropy?
a.
Ice
b.
steam
c.
liquid water at room temperature
d.
boiling water
 

 17. 

What changes when a gas is compressed?
a.
mass
c.
density
b.
moles
d.
all of the above
 

 18. 

Which of the following factors will NOT change the concentration of ammonia (NH3) in the reaction?
mc018-1.jpg?
a.
Decrease in the volume of N2.
c.
Decrease in pressure.
b.
Increase in the amount of catalyst.
d.
Decrease in temperature.
 

 19. 

In an exothermic reaction, equilibrium shifts _____ when temperature is raised.
a.
to the left
c.
to the center
b.
to the right
d.
none
 

 20. 

Which substance can dissolve only 40 g in 60°C water?
mc020-1.jpg
a.
NaCl
c.
KCl
b.
KClO3
d.
Ce2(SO4)3
 

 21. 

A very high value of the equilibrium constant for a reaction indicates that
a.
equilibrium is reached slowly.
c.
reactants are favored.
b.
equilibrium has been reached.
d.
products are favored.
 

 22. 

If the temperature of the equilibrium system X + Y « XY + 25 kJ decreases,
a.
the concentrations of reactants and products do not change.
b.
[X] decreases and [XY] decreases.
c.
[X] decreases and [XY] increases.
d.
[X] increases and [XY] decreases.
 

 23. 

Two liquids that can be mixed together but separate shortly after are:
a.
immiscible
c.
miscible
b.
insoluble
d.
soluble
 

 24. 

How much heat is evolved from 54.0 g glucose (C6H12O6), according to the equation for calculating heat?

mc024-1.jpg
a.
0.842 kJ
c.
84.2 kJ
b.
8.42 kJ
d.
842 kJ
 

 25. 

Calculate pH of an aqueous solution of hydrochloric acid. Given the hydrogen ion concentration is 8.75 × 10–9 M.
a.
7.85
c.
8.06
b.
7.81
d.
7.77
 

 26. 

When ice melts to form liquid water it’s enthalpy _____ and its entropy _____.
a.
increases, decreases
b.
decreases, decreases
c.
decreases, increases
d.
increases, increases
 

 27. 

When the volume of a gas decreases its pressure will ___ under constant temperature.
a.
increases.
b.
decreases.
c.
remains constant.
d.
It is impossible to tell because all gases are different.
 

 28. 

Which gas law has constant gas and volume?
mc028-1.jpg
a.
Boyle’s
c.
Combined
b.
Charles’s
d.
Gay-Lussac’s
 

 29. 

When temperature is lowered, pressure will _______ because _____.
a.
lower, particles slow down and collide less frequently with container walls.
c.
lower, particles slow down and decrease the volume of the container.
b.
lower, partilcles speed up and collide more frequently with container walls.
d.
increase, particles speed up and collide more frequently with container walls.
 

 30. 

Which of the following is true of particles of a gas?
a.
attract each other but do not collide.
b.
repel each other and collide.
c.
neither attract nor repel each other but collide.
d.
neither attract nor repel each other and do not collide.
 

 31. 

Based on the figure below, which of the following statements is true?
mc031-1.jpg
a.
The formation of AlCl3 began at 0.0oC.
c.
The final temperature of the products was -704oC.
b.
The final temperature of the reactants was -704oC.
d.
The formation of AlCl3 releases energy.
 

 32. 

What is happening to the energy of the universe in following image?
mc032-1.jpg
a.
not enough information to tell
b.
decreasing
c.
staying the same
d.
increasing
 

 33. 

Keq ___ 1: Reactants are favored at equilibrium.
a.
<
c.
+
b.
>
d.
=
 

 34. 

What is the equation for calculating heat?
a.
mc034-1.jpg m × q × mc034-2.jpg
c.
mc034-5.jpg c × m × mc034-6.jpg
b.
mc034-3.jpg c × q × mc034-4.jpg
d.
mc034-7.jpg c × m × q
 

 35. 

The property of water that describes water sticking to a tree branch is:
a.
cohesion
c.
adhesion
b.
anomaly
d.
polarity
 

 36. 

The _____ law of thermodynamics states that energy is neither created nor destroyed.
a.
first
c.
third
b.
second
d.
fourth
 

 37. 

A basic solution contains more _____ ions than hydrogen.
a.
oxygen
c.
hydroxide
b.
nitrogen
d.
sulfide
 

 38. 

A _____ is produced when a base accepts a hydrogen ion from an acid.
a.
conjugate acid
c.
acid
b.
conjugate base
d.
base
 

 39. 

In the Bronsted-Lowry model of acids and bases, a(n) _____ is a hydrogen donor and a(n) _____ is a hydrogen acceptor.
a.
acid, base
c.
conjugate acid, conjugate base
b.
base, acid
d.
conjugate base, conjugate acid
 

 40. 

What is the pH of blood, given the hydrogen ion concentration is 4.0 × 10-8 M?
a.
7.0
c.
7.4
b.
7.2
d.
7.6
 

 41. 

A collision requires _____ to be effective.
a.
only enough energy
b.
favorable orientation
c.
enough energy and favorable orientation
d.
a reaction mechanism
 

 42. 

In an endothermic reaction, equilibrium shifts _____ when temperature is lowered.
a.
to the left
c.
to the center
b.
to the right
d.
none
 

 43. 

What is the conjugate acid in the forward reaction?
mc043-1.jpg
a.
HF
c.
H2O
b.
H3O+
d.
mc043-2.jpg
 

 44. 

Keq ___ 1: Products are favored at equilibrium.
a.
<
c.
+
b.
>
d.
=
 

 45. 

What unknown quantity is calculated after performing a titration?
a.
concentration
c.
volume
b.
density
d.
mass
 

 46. 

According to Gay-Lussac’s law:
a.
pressure is inversely proportional to volume at constant temperature.
b.
pressure is directly proportional to temperature at constant volume.
c.
volume is inversely proportional to temperature at constant pressure.
d.
volume is directly proportional to temperature at constant pressure.
 

 47. 

Of all the water on earth the majority is:
a.
Salt water
c.
Liquid Water
b.
Water vapor
d.
Solid Ice
 

 48. 

A _____ reaction is a chemical reaction that can occur in both the forward and reverse directions.
a.
complete
c.
reversible
b.
forward
d.
incomplete
 

 49. 

A decrease in the concentration of reactants causes the rate of the _____ reaction to slow.
a.
complete
c.
reverse
b.
forward
d.
incomplete
 

 50. 

Which of the following is a measure of the disorder in a system?
a.
enthalpy
b.
entropy
c.
temperature
d.
free energy
 



 
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